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課程名稱 |
有機金屬化學
Organometallic Chemistry |
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開課學期 |
103-1 |
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授課對象 |
理學院 化學系 |
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授課教師 |
陳竹亭 |
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課號 |
Chem5017 |
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課程識別碼 |
223 U0550 |
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班次 |
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學分 |
2 |
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全/半年 |
半年 |
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必/選修 |
選修 |
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上課時間 |
星期二5,6(12:20~14:10) |
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上課地點 |
化210室 |
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備註 |
本課程中文授課,使用英文教科書。外系所學生欲選修，須經授課老師同意。與客座教授合開。
限學士班三年級以上 且 限本系所學生(含輔系、雙修生)
總人數上限：60人 |
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Ceiba 課程網頁 |
http://ceiba.ntu.edu.tw/1031Chem5017_ |
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課程簡介影片 |
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核心能力關聯 |
核心能力與課程規劃關聯圖 |
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課程大綱
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課程概述 |
Organometallic chemistry develops enormously in recent 60 years, because its wide range of important and useful applications in organic syntheses and catalyses. It also introduced many new fundamental concepts in chemistry. Lecture includes fundamental concepts of organotransition metal chemistry and their applications to organic syntheses and homogeneous catalyses. Only representative organic reactions will be employed here, since it is impossible to introduce huge accomplishments in this area.
來自日本的 碇屋隆雄(TTakao Ikariya)教授 會參與教學 |
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課程目標 |
Syllabus
[Chemistry of Molecular Catalysis]
1) Introduction to Organometallic Chemistry
2) General properties of Organometallic compounds
3) Bonding of Metal–Carbon of Metal–Hydrogen bond
4) Molecular Catalysis Based on Organometallic Compounds
5) Fundamental Reactions of Organometallic Compounds
1 Ligand dissociation and association
2 Oxidative addition and reductive elimination
3 Insertion and Elimination
4 Reaction of coordinated ligands
5 Transmetallation
6) Homogeneous Catalysis
1 Alkene hydrogenation
2 Alkene isomerization
3 Alkene polymerization
4 Hydroformylation
5 Catalytic transformation of Butadine
6 Alkene metathesis
7 C–C cross coupling reactions
8 Carbonylation
7) Asymmetric Catalysis
8) Molecular Catalysis in Supercritical Carbon Dioxide
9) Recent Progress in Bifunctional Catalysis
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課程要求 |
待補 |
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預期每週課後學習時數 |
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Office Hours |
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指定閱讀 |
Any Organomettalic or Inorganic Texbook
Organomettalic journals |
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參考書目 |
1.有機金屬化學(日文) 小宮三四郎、碇屋隆雄著
2. Organotransition Metal Chemistry Akio Yamamoto Wiley
3. Syntheisi of organometallic compounds S. Komiya Wiley
4. Organotranisiton metal chemistry "from bonding to catalysis" J. Hartwig,
UNiversity Science Books.2010. |
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評量方式
(僅供參考) |
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No. |
項目 |
百分比 |
說明 |
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1. |
Midterm |
50% |
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2. |
Final |
50% |
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週次 |
日期 |
單元主題 |
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第10週 |
11/18 |
Mid-term Test |
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第17週 |
1/06 |
Final Test |